COMMON TERMS IN ACTIVATED CARBON WORLD
ABRASION NUMBER
The abrasion number of granular carbon defines the resistance of the
particles to degrade on handling. It is calculated by contacting a carbon
sample with steel balls in a Ro-Tap machine and determining the percent
ratio of the final mean particle diameter to the original mean particle
diameter.
ACTIVATED CARBON
Activated carbon is a crude form of graphite, with a random or amorphous
structure, which is highly porous over a broad range of pore sizes, from
visible cracks and crevices to cracks and crevices of molecular dimensions.
ACID-WASHED
ACTIVATED CARBON Carbon which has been contacted with an acid solution with
the purpose of dissolving ash in the activated carbon.
ADSORBATE
That which is adsorbed on the adsorbent.
ADSRPBENT
Any solid having the ability to concentrate significant quantities of other
substances on its surface. Activated carbon is an adsorbent.
ADSORBER
A vessel designed to hold granular carbon.
ADSORPTION
The phenomenon whereby molecules adhere to a surface with which they come in
contact.
ADSORPTION ISOTHERMS
A measurement of adsorption determined at a constant temperature by varying
the amount of carbon used or the concentration of impurity in contact with
the carbon.
ADSORPTION PORES
The finest pores in the carbon structure. Pores which have adsorption
capabilities.
APPARENT DENSITY
The weight per unit volume of activated carbon.
ASH
The mineral oxide constituents of activated carbon. It is normally defined
as a weight percent basis after given amount of sample is oxidized.
BACKWASH
An operating method used to remove suspended solids from the carbon bed.
Water is pumped into the bottom of the adsorber, flows upward through the
carbon bed, and exits through the backwash outlet. The upward flow expands
the bed and removes the suspended solids, carbon fines, and entrained air.
The percent bed expansion and time required for backwashing is a function of
the backwash rate and water temperature.
BED DEPTH
The amount of carbon expressed in length units, which is parrallel to the
flow of the stream and through which the stream must pass.
BUTANE NUMBER
The volume of butane adsorbed per unit weight of activated carbon after air
saturated with butane is passed through a carbon bed at a given temperature
and pressure.
CARBON COLUMN
A column filled with granular activated carbon whose primary function is the
preferential adsorption of a particular type or types of molecules.
CARBON TETRACHLORIDE ACTIVITY (ctc)
The maximum percentage increase in weight of a bed of activated carbon after
air saturated with carbon tetrachloride is passed through it at a given
temperature.
CHEMI-SORPTION
Adsroption where the forces holding the adorbate to the adsorbent are
chemical (valence) instead of physical (London's).
COLOR BODIES
Those complex molecules which impart color (usually undesirable) to a
solution.
COUNTER CURRENT EFFIECIENCY
The unique advantage of a caron column that permits partially spent
activated carbon to adsorb impurities before the semi-processed stream comes
in contact with fresh carbon. This allows the maximum capasity of the
activated carbon to be utilized.
CRITICAL BED DEPTH
In a carbon column the critical bed depth is the depth of granular carbon
which is partially spent. It lies between the fresh carbon and the spent
carbon and is the zone where adsorption takes place. In a single column
system, this is the amount of carbon that is not completely utilized. See
MASS TRANSFER ZONE
CROSS SECTIONAL BED AREA
The area of activated carbon through which the stream flow is perpendicular.
DEAERATION
The process of removnig air (gases) from a bed of carbon particles. In a
volume of 1m3 of activated carbon, there are approximately 40% of void
space, 40% of pore volume and 20% of carbon skeleton.
DESORPTION
The opposite of adsorption. A phenomenon where an adsorbed molecule leaves
the surface of the adsorbent.
EDUCTORA
Device with no moving parts used to force an activated carbon water slurry
through pipes to the desired location.
HEAT OF ADSORPTION
The heat given off when molecules are adsorbed.
HARDNESS NUMBER
The hardness number is the resistance of a granular carbon to the
degradation action of steel balls in a Ro-Tap machine. It is calculated by
using the weight of granular carbon retained on a particular sieve after the
carbon has been in contact with steel balls.
IODINE NUMBER
The iodine number is the milligrams of iodine adsorbed by one gram of carbon
at a filtrate concentration of 0.02N iodine.
MAKE UP CARBON
Fresh granular activated carbon which must be added to a column system after
a regeneration cycle or when deemed necessary to bring the total amount of
carbon to specification.
MACROPORE
See Transport porse
MASS TRANSFER ZONE
The adsorption gradient that exists in the carbon bed. It corresponds to the
gradual transition of the carbon from "fresh" (or "virgin") to "spent" (or
"exhausted").
MESH SIZE
The particle size of granular activated carbon as determined by the U.S.
Sieve Series. Particle size distribution within a mesh series is given in
the specifications of the particular activated carbon.
MOLASSES NUMBER
The molasses number is calculated from the ratio of the optical densities of
the filtrate of a molasses solution treated with a standard activated carbon
and the activated carbon in question.
METHYLENE BLUE NUMBER
The methylene blue number is the milligrams of methylene blue adsorbed by
one gram of carbon in equilibrium with a solution of methylene blue having a
concentration of 1.0 mg per liter.
MOISTURE
The percent by weight of water adsorbed on activated carbon.
MOVING BED
A unique application with granular carbons in which a single carbon column
offers the efficiency of several columns in series. This is accomplished by
the removal of spent carbon from one end of the carbon bed and the addition
of fresh carbon at the other end with little or no interuption in the
process.
PARTICLE DENSITY
The weight per unit volume of granular activated carbon not including the
voids between the particles and cracks larger than 0.1 mm. It is determined
by the displacement by granular activated carbon in mercury and in helium at
standard conditions.
PORE VOLUME
The volume of the internal void spaces in a granule, smaller than 0.1 mm and
large enough to allow access to helium. It is measured as the difference in
the voulumetric displacement by granular activated carbon in mercury and in
helium at standard conditions.
REAL DENSITY
The density of the skeleton of a carbon granule. This is determined by
helium displacement.
REACTIVATION
The removal of adsorbates from spent granular activated carbon which will
allow the carbon to be reused and recycled.
SPECIFIC HEAT
The quantity of heat required to raise the temperature of a unit weight of
granular activated carbon through a particular interval of temperature
divided by the corresponding quantity for water. Typical value for Granular
Activated Carbon is 0.25. It should be noted that the thermal conductivity
of granular activated carbon is extremely low.
SURFACE AREA
The surface area of granular activated carbon is empirically determined by
the Brunauer, Emmett and Teller Method, which utilizes the adsorption of
nitrogen at liquid nitrogen temperature in the calculation. Surface area is
usually expressed in square meters per gram of carbon. Typical carbons range
from 600 to 2,200 square meters per gram.
TRANSPORT PORES
Pores larger than the largest adsorption pores. They function as a diffusion
path to transport adsorbates. Adsorption does not occur in these locations
even at near saturated conditions.
VOIDS
The percent by volume of the interstices to total bed volume.
WAVE FRONT
The carbon loading gradient that exists in the critical bed depth. It
corresponds the gradual transition of the carbon from "fresh" (or "virgin")
to "spent" (or "exhausted").